期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 136, 期 18, 页码 6590-6593出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja5028138
关键词
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资金
- National Basic Research Program of China (973 Program) [2010CB833300]
- National Natural Science Foundation of China [21025209, 21121062, 21332009]
A highly efficient synthesis of chiral polysubstituted 2H-pyrrole derivatives via a Pd-catalyzed intermolecular asymmetric allylic dearomatization reaction of pyrroles is presented. With the commercially available palladium precursor and chiral ligand, the polysubstituted 2H-pyrrole products containing a chiral quaternary carbon center were obtained with up to 97% ee and >95/5 regioselectivity.
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