期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 136, 期 4, 页码 1222-1225出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja411379e
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资金
- National Institutes of Health (NIH) [2R01GM068433]
- Alexander von Humboldt Foundation
- Grants-in-Aid for Scientific Research [23225002] Funding Source: KAKEN
A simple, efficient, and environmentally friendly asymmetric epoxidation of primary, secondary, tertiary allylic, and homoallylic alcohols has been accomplished. This process was promoted by a tungsten-bishydroxamic acid complex at room temperature with the use of aqueous 30% H2O2 as oxidant, yielding the products in 84-98% ee.
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