期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 136, 期 36, 页码 12548-12551出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja5058482
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资金
- U.S. National Institutes of Health [DK098446, GM105938]
- U.S. National Science Foundation [CHE-1012422]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1012422] Funding Source: National Science Foundation
A commercially available ruthenium(II) PNP-type pincer catalyst (Ru-Macho) promotes the formation of alpha-chiral tert-butanesulfinylamines from racemic secondary alcohols and Ellmans chiral tert-butanesulfinamide via a hydrogen borrowing strategy. The formation of alpha-chiral tert-butanesulfinylamines occurs in yields ranging from 31% to 89% with most examples giving >95.5 dr.
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