期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 136, 期 10, 页码 4075-4080出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja500878c
关键词
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资金
- 973 Program [2011CB808600]
- NSFC [21172176, 21372180]
- Hubei Province NSF [ZRZ0273]
- [NCET-10-0649]
- [2011YQ12003504]
An unprecedented Cu(I)-catalyzed asymmetric [6 + 3] cycloaddition of tropone with azomethine ylides was reported, which performs well over a broad scope of substrates and offers a unique and facile access to the synthetically useful bridged azabicyclo[4.3.1]decadiene derivatives in good yields with high levels of diastereoselectivities and enantioselectivities under mild conditions.
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