期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 136, 期 21, 页码 7543-7546出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja5019095
关键词
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资金
- Japan Society for the Promotion of Science
- ERATO Kitagawa Integrated Pores Project
- ACCEL Project from the Japan Science and Technology Agency
- Grants-in-Aid for Scientific Research [13F03032, 25870360] Funding Source: KAKEN
A porous coordination polymer (PCP) has been synthesized employing an organic ligand in which a stable free radical, isoindoline nitroxide, is incorporated. The crystalline PCP possesses one-dimensional channels decorated with the nitroxyl catalytic sites. When O-2 gas or air was used as the oxidant, this PCP was verified to be an efficient, recyclable, and widely applicable catalyst for selective oxidation of various alcohols to the corresponding aldehydes or ketones.
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