期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 136, 期 45, 页码 15865-15868出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja508860b
关键词
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资金
- NSF [1255519, 0903787]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1255519] Funding Source: National Science Foundation
Atomically precise thiolate-protected noble metal molecular nanoparticles are a promising class of model nanomaterials for catalysis, optoelectronics, and the bottom-up assembly of true molecular crystals. However, these applications have not fully materialized due to a lack of ligand exchange strategies that add functionality, but preserve the properties of these remarkable particles. Here we present a method for the rapid (<30 s) and complete thiolate-for-thiolate exchange of the highly sought after silver molecular nanoparticle [Ag-44(SR)(30)](-4). Only by using this method were we able to preserve the precise nature of the particles and simultaneously replace the native ligands with ligands containing a variety of functional groups. Crucially, as a result of our method we were able to process the particles into smooth thin films, paving the way for their integration into solution-processed devices.
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