期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 136, 期 52, 页码 17899-17901出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja5109535
关键词
-
资金
- [24000009]
- Grants-in-Aid for Scientific Research [24000009, 12J05611] Funding Source: KAKEN
We have developed a new synthetic protocol for the preparation of a microcrystalline powder (median size: X-50 = 25 mu m) of networked M6L4 cages 1a for the stationary phase of an affinity column on a greater than 50 g scale. Analogously to large single crystals 1b (X-50 approximate to 0.5 mm), microcrystals 1a accommodate guest molecules tetrathiafulvalene (TTF) and fullerene (C-60) at up to 32 and 35 wt %, respectively. Importantly, the hostguest interactions within networked cages could be evaluated in terms of the retention time from HPLC analysis by using microcrystals 1a as the stationary phase. In this way, favorable guests for networked cages 1 and even solution M6L4 cage 2 could easily be assessed by HPLC.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据