期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 136, 期 35, 页码 12209-12212出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja504995f
关键词
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资金
- Ministry of Education, Culture, Sports, Science and Technology of Japan [21225004]
- RIKEN
- Grants-in-Aid for Scientific Research [26220802] Funding Source: KAKEN
Cationic half-sandwich scandium alkyl complexes bearing monocyclopentadienyl ligands embedded in chiral binaphthyl backbones act as excellent catalysts for the enantioselective C-H bond addition of pyridines to various 1-alkenes, leading to formation of a variety of enantioenriched alkylated pyridine derivatives in high yields and excellent enantioselectivity (up to 98:2 er).
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