期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 136, 期 33, 页码 11606-11609出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja5061609
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资金
- Basic Science Research Program through the National Research Foundation of Korea (NRF) - Ministry of Education, Science and Technology [2013R1A1A1009618]
- Kangwon National University [C1009162-01-001]
- National Research Foundation of Korea [2013R1A1A1009618] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
Air-stable azomethine ylides with an unusual pattern of charge distribution were efficiently prepared via the rhodium-catalyzed reaction between pyridines and 1-sulfonyl-1,2,3-triazoles. This reaction allowed for the first example of the catalytic multicomponent [5 + 2] cycloaddition reactions, thus resulting in the formation of biologically active 1,4-diazepine compounds.
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