期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 136, 期 30, 页码 10807-10813出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja505737x
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资金
- Scripps Research Institute
- NSF under the CCI Center for Selective C-H Functionalization [CHE-1205646]
- Shanghai Jiao Tong University
- China Scholarship Council
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1205646] Funding Source: National Science Foundation
meta-C-H olefination, arylation, and acetoxylation of indolines have been developed using nitrile-containing templates. The combination of a monoprotected amino acid ligand and the nitrile template attached at the indolinyl nitrogen via a sulfonamide linkage is crucial for the meta-selective C-H fiunctionalization of electron-rich indolines that are otherwise highly reactive toward electrophilic palladation at the para-positions. A wide range of synthetically important and advanced indoline analogues are selectively functionalized at the meta-positions.
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