期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 136, 期 25, 页码 8915-8918出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja5046296
关键词
-
资金
- National Institutes of Health [R01 GM85235]
A method for the enantioselective, intramolecular sulfenoamination of various olefins has been developed using a chiral BINAM-based selenophosphoramide, Lewis base catalyst. Terminal and trans disubstituted alkenes afforded pyrrolidines, piperidines, and azepanes in high yields and high enantiomeric ratios via enantioselective formation and subsequent stereospecific capture of the thiiranium intermediate with the pendant tosyl-protected amine.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据