4.8 Article

Microwave Synthesis of Microstructured and Nanostructured Metal Chalcogenides from Elemental Precursors in Phosphonium Ionic Liquids

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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 136, 期 44, 页码 15465-15468

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AMER CHEMICAL SOC
DOI: 10.1021/ja508628q

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  1. Center for Energy Efficient Materials, an Energy Frontier Research Center - U.S. Department of Energy, Office of Science, Basic Energy Sciences [DE-SC0001009]
  2. National Science Foundation [DMR 0805148]
  3. MRSEC Program of the NSF [DMR 1121053]
  4. NSF
  5. Direct For Mathematical & Physical Scien
  6. Division Of Materials Research [0805148] Funding Source: National Science Foundation

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We describe a general approach for the synthesis of micro-/nanostructured metal chalcogenides from elemental precursors. The excellent solubility of sulfur, selenium, and tellurium in phosphonium ionic liquids promotes fast reactions between chalcogens and various metal powders upon microwave heating, giving crystalline products. This approach is green, universal, and scalable

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