期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 136, 期 16, 页码 5904-5907出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja502270y
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资金
- Institute of Basic Science (IBS)
- Ministry of Science, ICT & Future Planning, Republic of Korea [IBS-R010-D1-2014-A00] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
Described herein is the development of an iridium-catalyzed direct C-H amination of benzamides with anilines at room temperature, representing a unique example of an Ir catalyst system that is compatible with external oxidants. Mechanistic details, such as the isolation and characterization of key iridacycle intermediates, are also discussed.
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