4.8 Article

Construction of a Highly Symmetric Nanosphere via a One-Pot Reaction of a Tristerpyridine Ligand with Ru(II)

期刊

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 136, 期 23, 页码 8165-8168

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AMER CHEMICAL SOC
DOI: 10.1021/ja502962j

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资金

  1. National Science Foundation [CHE-1151991, CHE-1012636, CHE-1308307]
  2. China Scholarship Council (CSC)
  3. National Natural Science Foundation of China [21371103]
  4. Division Of Chemistry
  5. Direct For Mathematical & Physical Scien [1151991, 1308307] Funding Source: National Science Foundation

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A three-dimensional, highly symmetric, terpyridine-based, spherical complex was synthesized via the coordination of four novel, trisdentate ligands and six Ru2+ ions, and it exhibits excellent stability over a wide range of pH values (1-14). Structural confirmation was obtained by NMR and ESI-TWIM-MS.

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