期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 136, 期 6, 页码 2236-2239出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja412107b
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资金
- ICIQ Foundation
- European Research Council [ERC-277883]
- MICINN [CTQ2012-34054]
- ICREA Funding Source: Custom
A Ni/Cu-catalyzed silylation of unactivated C-O electrophiles derived from phenols or benzyl alcohols is described. This transformation is characterized by its wide scope and mild conditions, providing a direct access to synthetically versatile silylated compounds. The protocol allows for the coupling of C(sp(2))-O and even C(sp(3))-O bonds with similar efficiency.
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