期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 136, 期 52, 页码 17910-17913出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja510048b
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资金
- University of Hong Kong under the University Research Committee (URC) Strategic Research Theme on New Materials
- University Grants Committee Areas of Excellence (AoE) Scheme [AoE/P-03/08]
- General Research Fund (GRF) grant from the Research Grants Council of Hong Kong Special Administrative Region, P. R. China [HKU 7060/12P]
- University of Hong Kong
An alkynylplatinum(II) terpyridine complex functionalized with polyhedral oligomeric silsesquioxanes (POSS) moieties has been demonstrated to exhibit self-association behavior to give various distinguishable nanostructures with interesting morphological transformation from rings to rods in response to solvent conditions through the stabilization of Pt...Pt and pi-pi stacking interactions as well as hydrophobichydrophobic interactions. These changes can be systemically controlled by varying the solvent composition and have been studied by H-1 NMR, electron microscopy, UVvis absorption, and emission spectroscopies.
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