期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 136, 期 42, 页码 14654-14657出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja506978c
关键词
-
资金
- Centre National de la Recherche Scientifique
- Universite de Toulouse
- Agence Nationale de la Recherche [ANR-10-BLAN-0709]
- HPC resources of Idris under Allocation 2014 [i2014080045]
- Agence Nationale de la Recherche (ANR) [ANR-10-BLAN-0709] Funding Source: Agence Nationale de la Recherche (ANR)
Thanks to rational ligand design, the first gold(I) complexes to undergo oxidative addition of aryl iodides were discovered. The reaction proceeds under mild conditions and is general. The ensuing aryl gold(III) complexes have been characterized by spectroscopic and crystallographic means. DFT calculations indicate that the bending induced by the diphosphine ligand plays a key role in this process.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据