4.8 Article

Ligand-Controlled, Tunable Silver-Catalyzed C-H Amination

期刊

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 136, 期 48, 页码 16720-16727

出版社

AMER CHEMICAL SOC
DOI: 10.1021/ja5094309

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资金

  1. National Science Foundation [DMR-1206700]
  2. Office of Science, Office of Basic Energy Sciences, of the U.S. Department of Energy [DE-AC02-05CH11231]
  3. Division Of Chemistry
  4. Direct For Mathematical & Physical Scien [1254397] Funding Source: National Science Foundation

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The development of readily tunable and regioselective C-H functionalization reactions that operate solely through catalyst control remains a challenge in modern organic synthesis. Herein, we report that simple silver catalysts supported by common nitrogenated ligands can be used to tune a nitrene transfer reaction between two different types of C-H bonds. The results reported herein represent the first example of ligand-controlled and site-selective silver-promoted C-H amination.

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