期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 135, 期 28, 页码 10503-10511出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja404234n
关键词
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资金
- Spanish MICINN [CTQ2011-24187/BQU, CSD2007-00010]
- Comunidad de Madrid [MADRISOLAR-2, S2009/PPQ/1533]
- EU [FP7- ICT-2011.3.6, 287818]
- Fonds der Chemischen Industrie (FCI)
- Deutsche Forschungsgemeinschaft [SFB 583]
- Solar Technologies Go Hybrid initative by the state of Bavaria
Four new subphthalocyanine-based capsules have been synthesized and characterized. These supramolecular systems have been successfully employed for the encapsulation of fullerenes and probed by a wide range of characterization methods, including NMR, UV-vis and fluorescence spectroscopy, electrospray ionization mass spectrometry, and electrochemistry. Furthermore, the binding constants of the host guest complexes were estimated. Finally, the photophysical properties revealed that the subphthalocyanines undergo a transduction of singlet excited-state energy to the fullerene inside the cavity upon photoexcitation.
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