期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 135, 期 39, 页码 14480-14483出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja403954g
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资金
- European Research Council (ERC) [307948]
- Forschungskredit of UZH
- Novartis Foundation
- European Research Council (ERC) [307948] Funding Source: European Research Council (ERC)
A novel copper-catalyzed one-pot trifluoromethylation/aryl migration/desulfonylation and C(sp(2))-N bond formation with conjugated tosyl amides as starting materials is presented here. The reaction affords alpha-aryl-beta-trifluoromethyl amides bearing a quaternary stereocenter or trifluoromethylated oxindoles in a regioselective manner.
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