期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 135, 期 47, 页码 17667-17670出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja407764u
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资金
- MEXT (Japan)
- Japanese Government (MEXT)
- Grants-in-Aid for Scientific Research [21000006] Funding Source: KAKEN
We developed herein a new chiral Bronsted acid catalyst which is composed of two independent organic molecules, a chiral diol, and 2-boronobenzoic acid. In situ formation of a boronate ester was utilized as a key process to generate an active catalyst. This boronate ester assisted chiral carboxylic acid catalyst was successfully applied to the trans-aziridination of N-Boc and N-benzyl imines with N-phenyldiazoacetamide. This is the first catalyst to achieve high enantioselectivities using N-benzyl imines.
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