期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 135, 期 24, 页码 9200-9203出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja404084p
关键词
-
资金
- Deutsche Forschungsgemeinschaft [GRK 1570, SPP 1243]
- Volkswagen Foundation
- Nederlandse Organisatie voor Wetenschappelijk Onderzoek (NWO/Chemical Sciences) [722.011.007]
Metal-organic complexes were formed by means of inelastic excitations in a scanning tunneling microscope (STM). The electronic structure of the complex was characterized using STM imaging and spectroscopy. By exploiting the symmetry of the complex, its electronic structure can be rationalized from linear combinations of molecular orbitals. The actual bonding geometry, which cannot be inferred from STM alone, was determined from atomic force microscopy images with atomic resolution. Our study demonstrates that the combination of these techniques enables a direct quantification of the interplay of geometry and electronic coupling in metal-organic complexes in real space.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据