期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 135, 期 32, 页码 11720-11723出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja405495u
关键词
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资金
- DTRA [HDTRA1-10-1-0023]
- Weinberg College of Arts and Sciences, Northwestern University
- NSF-NSEC
- NSF-MRSEC
- Keck Foundation
- state of Illinois
- Northwestern University
An Al(porphyrin) functionalized with a large axial ligand was incorporated into a porous organic polymer (POP) using a cobalt-catalyzed acetylene trimerization strategy. Removal of the axial ligand afforded a microporous POP that is catalytically active in the methanolysis of a nerve agent simulant. Supercritical CO2 processing of the POP dramatically increased the pore size and volume, allowing for significantly higher catalytic activities.
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