期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 135, 期 43, 页码 16006-16009出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja407654n
关键词
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资金
- Major State Basic Research Development Program [2013CB922102]
- NSFC [91022031, 21021062, 21101093]
- NSF of Jiangsu province [BK2011548]
A series of end-to-end azido-bridged perovskite-type compounds [(CH3)(n)NH4-n][Mn(N-3)(3)] (n = 1-4) were synthesized and characterized. Structural phase transitions indicating the general lattice flexibility were observed and confirmed by the crystal structures of different phases. These materials show cation-dependent magnetic ordering at up to 92 K and magnetic bistability near room temperature.
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