期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 136, 期 2, 页码 801-809出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja411626v
关键词
-
资金
- MEC [CTQ2010-16088/BQU]
- European Research Council [321066]
- EU Project ICT (ATMOL) [FP7-270028]
- AGAUR [2009 SGR 47]
- ICIQ Foundation
The fate of the aryl gold(I) carbenes generated by retro-Buchner reaction of ortho-substituted 7-aryl-1,3,5-cycloheptatrienes is dependent on the constitution of the ortho substituent. Indenes and fluorenes are obtained by intramolecular reaction of highly electrophilic gold(I) carbenes with alkenes and arenes. According to density functional theory calculations, the gold-catalyzed retro-Buchner process occurs stepwise, although the two carbon-carbon cleavages occur on a rather flat potential energy surface.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据