期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 136, 期 1, 页码 96-99出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja411423a
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资金
- U.S. Department of Energy, Office of Basic Energy Sciences, Chemical Sciences, Biosciences, and Geosciences Division [DE-FG02-09ER16067]
Addition of KSCPh3 to [U(NR2)(3)] (R = SiMe3) in tetrahydrofuran, followed by addition of 18-crown-6, results in formation of the U(IV) sulfide, [K(18-crown-6)][U(S)(NR2)(3)] (1) and Gomberg's dimer. Similarly, addition of KOCPh3 to [U(NR2)(3)] in tetrahydrofuran, followed by addition of 18-crown-6, results in formation of the U(IV) oxide, [K(18-crown-6)][U(O)-(NR2)(3)] (3). Also observed in this transformation are the triphenylmethyl anion, [K(18-crown-6)(THF)(2)][CPh3] (5), and the U(IV) alkoxide, [U(OCPh3)(NR2)(3)] (4).
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