期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 135, 期 24, 页码 8806-8809出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja403580J
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资金
- Institute for Basic Science in Korea
- Ministry of Science, ICT & Future Planning, Republic of Korea [IBS CA1301] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
Multiamines with amphiphilic structures have been synthesized to serve as simultaneous structure-directing agents in micro- and meso-structural levels for aluminophosphate materials (AlPOs) and their analogues, such as silicoaluminophosphate, cobalt aluminophosphate, and gallium phosphate. The amine molecules are assembled into a micelle with a specific morphology to function as a mesa-level structure director. Individual amine groups in the micelle are able to direct the formation of microporous crystalline AlPO structure. The resultant meso-level morphologies of the AlPOs are typically nanosheets of uniform thickness, which can be tailored in the range of 2-5 nm by the number of amine groups. Sponge-like disordered mesoporous morphologies can be generated, depending on the amine structures. Using such multiamines provides a versatile route to various phosphate materials with a structural hierarchy for enhanced porous functionalities.
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