期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 135, 期 11, 页码 4167-4170出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja3110544
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资金
- National Institutes of Health [NIGMS R01 GM063540]
A palladium-catalyzed 1,4-addition across the commodity chemical 1,3-butadiene to afford skipped polyene products is reported. Through a palladium sigma -> pi -> sigma allyl isomerization, two new carbon-carbon bonds are formed with high regioselectivity and trans stereoselectivity of the newly formed alkene. The utility of this method is highlighted by the successful synthesis of the ripostatin A skipped triene core.
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