4.8 Article

Organocatalytic C-H/C-H′ Cross-Biaryl Coupling: C-Selective Arylation of Sulfonanilides with Aromatic Hydrocarbons

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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 135, 期 38, 页码 14078-14081

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AMER CHEMICAL SOC
DOI: 10.1021/ja407944p

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资金

  1. Japan Society for the Promotion of Science (JSPS)
  2. The Ministry of Education, Culture, Sports, Science and Technology (MEXT)
  3. Ritsumeikan Global Innovation Research Organization (R-GIRO) project
  4. JSPS
  5. Grants-in-Aid for Scientific Research [25860017, 24689002] Funding Source: KAKEN

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The hypervalent iodine-mediated C-C selective coupling of N-methanesulfonyl anilides with aromatic hydrocarbons has been developed. The first organocatalytic oxidative cross-biaryl-coupling was achieved by the catalyst control in defining specific 2,2'-diiodobiphenyls for the direct C-C bond formations.

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