期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 135, 期 7, 页码 2462-2465出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja312380b
关键词
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资金
- MEXT of Japan [24750054, 21108002]
- JSPS
- Grants-in-Aid for Scientific Research [21108002, 12J10449, 21108001, 13J08382, 21108004, 23245029] Funding Source: KAKEN
A pi-conjugated nanosheet comprising planar nickel bis(dithiolene) complexes was synthesized by a bottom-up method. A liquid-liquid interfacial reaction using benzenehexathiol in the organic phase and nickel(II) acetate in the aqueous phase produced a semiconducting bulk material with a thickness of several micrometers. Powder X-ray diffraction analysis revealed that the crystalline portion of the bulk material comprised a staggered stack of nanosheets. A single-layer nanosheet was successfully realized using a gas-liquid interfacial reaction. Atomic force microscopy and scanning tunneling microscopy confirmed that the pi-conjugated nanosheet was single-layered. Modulation of the oxidation state of the nanosheet was possible using chemical redox reactions.
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