期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 135, 期 32, 页码 11760-11763出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja406556h
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资金
- Marie Curie Intra-European Fellowship [273807]
- Heriot-Watt University
- ERC Starting Investigator Grant (ASPiRe)
- Walters-Kundert Foundation
- EPSRC [EP/F035535/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/F035535/1] Funding Source: researchfish
Herein we report the photocontrol of cucurbit[8]uril (CB[8])-mediated supramolecular polymerization of azobenzene-containing monomers. The CB[8] polymers were characterized both in solution and in the solid state. These host guest complexes can be reversibly switched between highly thermostable photostationary states. Moreover, a remarkable stabilization of Z-azobenzene was achieved by CB[8] complexation, allowing for structural characterization in the solid state.
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