期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 135, 期 22, 页码 8125-8128出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja402630g
关键词
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资金
- National Science Foundation of China [91122017]
- Program for Changjiang Scholars and Innovative Research Team in University [IRT1117]
- National Basic Research Program of China [2010DFA41160, 2011CB808505]
- Shanghai Science and Technology Committee [12DZ2275100]
- NUS [R143-000-492-598, R143-000-426-305]
A series of Cp*Rh-based functional metallarectangles have been synthesized from metallaligands. Enlargement of one linker leads to the isolation of two novel Borromean link architectures. All these complexes are intact in solution, as evident from ESI-MS spectroscopic analysis. Arising from the combination of open Cu centers and favorable cavity space, {(Cp*Rh)(4)(bpe)(2)[Cu-(opba)center dot 2MeOH](2)}4(OTf)center dot 6MeOH shows extraordinary catalytic abilities with high efficiency and wide substrate selectivity in the acyl-transfer reaction.
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