期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 135, 期 34, 页码 12556-12559出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja4063019
关键词
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资金
- Vanier Canada Graduate Scholarship
- NSERC Discovery Grant
- Canada Foundation for Innovation Leader's Opportunity Fund
- FRQNT Nouveaux Chercheurs program
Unusually long thermal half-lives of perhalogenated cis-azobenzenes enabled their structural characterization and the first evidence of a crystal-to-crystal cis -> trans azobenzene isomerization. Irradiation with visible light transforms a perhalogenated cis-azobenzene single crystal into a polycrystalline aggregate of its trans-isomer in a photomechanical transformation that involves a significant, controllable, and thermally irreversible change of crystal shape. This is the first demonstration of permanent photomechanical modification of crystal shape in an azobenzene.
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