4.8 Article

Copolymerization of Epoxides with Carbon Dioxide Catalyzed by Iron-Corrole Complexes: Synthesis of a Crystalline Copolymer

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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 135, 期 23, 页码 8456-8459

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AMER CHEMICAL SOC
DOI: 10.1021/ja4028633

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  1. Funding Program for World-Leading Innovative R&D on Science and Technology from the Japan Society for the Promotion of Science (JSPS)

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Iron-corrole complexes were found to copolymerize epoxides with CO2. The first iron-catalyzed propylene oxide/CO2 copolymerization has been accomplished. Moreover, the glycidyl phenyl ether (GPE)/CO2 copolymerization with this catalyst provided a crystalline material as a result of the isotactic poly(GPE) moiety.

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