期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 135, 期 10, 页码 3736-3739出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja309744c
关键词
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资金
- Creative Research Initiative [2010-0018286]
- WCU [R32-10217]
- KBSI-HVEM [JEM-ARM 1300S]
Two-dimensional (2D) layered nanostructures are emerging fast due to their exceptional materials properties. While the importance of physical approaches (e.g., guest intercalation and exfoliation) of 2D layered nanomaterials has been recognized, an understanding of basic chemical reactions of these materials, especially in nanoscale regime, is obscure. Here, we show how chemical stimuli can influence the fate of reaction pathways of 2D layered nanocrystals. Depending on the chemical characteristics (Lewis acid (O-1(2)) or base (H2O)) of external stimuli, TiS2 nanocrystal is respectively transformed to either a TiO2 nanodisc through a compositional metathesis or a TiO2 toroid through multistage edge-selective structural transformation processes. These chemical reactions can serve as the new design concept for functional 2D layered nanostructures. For example, TiS2(disc)-TiO2(shell) nanocrystal constitutes a high performance type II heterojunction which not only a wide range solar energy coverage (similar to 80%) with near-infrared absorption edge, but also possesses enhanced electron transfer property.
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