期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 135, 期 15, 页码 5557-5560出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja4023557
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资金
- National Science Foundation [DGE-1144469]
- California Institute of Technology
- Amgen
- DuPont
- NIH [NIGMS RGM097582A]
A copper-catalyzed arylation of tryptophan derivatives is reported. The reaction proceeds with high site- and diastereoselectivity to provide aryl pyrroloindoline products in one step from simple starting materials. The utility of this transformation is highlighted in the five-step syntheses of the natural products (+)-naseseazine A and B.
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