期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 135, 期 24, 页码 8778-8781出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja402262x
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资金
- NSF [CHE-1152294]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1152294] Funding Source: National Science Foundation
External control over the rate of dynamic methyl group exchange between configurationally stable active species and configurationally unstable dormant species with respect to chain-growth propagation within a highly stereoselective and regiospecific living coordination polymerization of 1,6-heptacliene has been used to generate a spectrum of different physical forms of poly(1,3-methylenecyclohexane) (PMCH) in which the stereochemical microstructure has been systematically varied between two limiting forms. The application of this strategy to manipulate the bulk properties of PMCH and the solid-state microphase behavior of well-defined PMCH-b-poly(1-hexene) block copolymers is further demonstrated.
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