期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 135, 期 37, 页码 13695-13698出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja4057932
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We describe a new synthetic approach to regioregular monodisperse oligo(3-allcylthiophene)s allowing for simple separation of regioregular material in gram quantities. The number of repeat units follows the Fibonacci numbers up to a length of 21. In a small adaption of this approach, introduction of a protecting group was used to synthesize an oligo(3-hexylthiophene) with 36 repeating units, the longest regioregular 3-hexylthiophene oligomer synthesized to date.
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