期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 135, 期 7, 页码 2486-2488出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja400219d
关键词
-
资金
- National Science Foundation [CHE-0953484, CHE-1057466, CHE-1054286]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1265212] Funding Source: National Science Foundation
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1054286, 0953484, 1057466] Funding Source: National Science Foundation
Oxidation of carbene-stabilized diarsenic, L:As-As:L [L: = :C{N(2,6-(Pr2C6H3)-Pr-1)CH}(2)] (1), with gallium chloride in a 1:4 ratio in toluene affords the dicationic diarsene complex [L:As = As:L](2+)([GaCl4](-))(2) (2(2+)[GaCl4](2)), while oxidation of 1 with GaCl3 in a 1:2 ratio in Et2O yields the monocationic diarsenic radical complex [L:AsAs:L](center dot+)[GaCl4](-) (2(center dot+)[GaCl4]). Strikingly, complex 2(center dot+) is the first arsenic radical to be structurally characterized in the solid state. The nature of the bonding in these complexes was probed computationally and spectroscopically.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据