期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 135, 期 8, 页码 2975-2978出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja4004377
关键词
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资金
- EU [275212]
- Clare Hall, University of Cambridge
- EPSRC
- EU ERC
We show that natural abundance oxygen-17 NMR of solids could be obtained in minutes at a moderate magnetic field strength by using dynamic nuclear polarization (DNP). Electron spin polarization could be transferred either directly to O-17 spins or indirectly via H-1 spins in inorganic oxides and hydroxides using an oxygen-free solution containing a biradical polarization agent (bTbK). The results open up a powerful method for rapidly acquiring high signal-to-noise ratio solid-state NMR spectra of O-17 nuclear spins and to probe sites on or near the surface, without the need for isotope labeling.
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