期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 135, 期 24, 页码 9099-9110出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja4035335
关键词
-
资金
- A*Star [SERC 112-120-2011]
- NRF of Singapore [CRP-4-2008-06]
Growing oxide shells on seed nanoparticles requires the control of several processes: (a) the nucleation and growth of the shell material; (b) the wetting of the shell material on the seeds; and (c) the aggregation of the nanoparticles. These processes are influenced by a number of factors, many of which are related. Without understanding the interdependence of these contributing factors, it is difficult to circumvent problems and achieve rational synthesis. We first did a case study on encapsulating Au nanoparticles with ZnO to understand the multiple roles of polyvinylpyrrolidone (PVP) and their dependence on other factors. We developed a general method for coating ZnO on a variety of seeds, including metals, oxides, polymer nanoparticles, graphene oxide, and carbon nanotube. This method can be further extended to include Fe3O4, MnO, Co2O3, TiO2, Eu2O3, Tb2O3, Gd2O3, beta-Ni(OH)(2), ZnS, and CdS as the shell materials. The understanding obtained in this systematic study will aid rational design and synthesis of other core-shell nanostructures.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据