期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 135, 期 23, 页码 8720-8725出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja403232d
关键词
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资金
- WCU (World Class University) Program [R31-2008-000-20012-0]
- Basic Science Research Program [2011-0013601]
- Center for Advanced Soft Electronics under the Global Frontier Research Program [2011-0031630]
- Converging Research Center Program through the National Research Foundation [2012K001251]
- MEST of Korea
With the exploding interest in transition metal chalcogenides, sulfide minerals containing the dianion S-2(2-), such as pyrite (FeS2), cattierite (CoS2), and vaesite (NiS2), have recently attracted much attention for potential applications in energy conversion and storage devices. However, the synthesis of the patronite structure (VS4, V4+(S-2(2-))(2)) and its applications have not yet been clearly demonstrated because of experimental difficulties and the existence of nonstoichiometric phases. Herein, we report the synthesis of VS4 using a simple, facile hydrothermal method with a graphene oxide (GO) template and the characterization of the resulting material. Tests of various templates such as CNT, pyrene, perylene-3,4,9,10-tetracarboxylic dianhydride (PTCDA), and graphite led us to the conclusion that the graphitic layer plays a role in the nucleation during growth of VS4. Furthermore, the VS4/rGO hybrid was proved to be a promising functional material in energy storage devices.
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