期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 135, 期 11, 页码 4187-4190出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja400490u
关键词
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资金
- Ministry of Science and Technology of China [2013CB933402, 2011CB932601]
- National Natural Science Foundation of China [21171013, 21241004]
- Natural Science Foundation of Jiangsu Province [BK2012611]
We report the synthesis, isolation, and characterizations of the novel trimetallofullerene Sm-3@I-h-C-80. Importantly, the experimental X-ray structure of Sm-3@I-h-C-80 verified for the first time that three metal atoms can be stabilized in a fullerene cage without a nonmetal mediator. Furthermore, computational studies demonstrated the electronic features of Sm-3@I-h-C-80, which are similar to that of theoretically studied Y-3@I-h-C-80. Electrochemical studies of Sm-3@I-h-C-80 showed a major difference from those of the well-studied isoelectronic species Sc3N@I-h-C-80 and La-2@I-h-C-80.
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