期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 135, 期 47, 页码 17747-17750出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja410389a
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资金
- UT Austin
- CPRIT
- Welch Foundation [F-1781]
Herein we report a direct beta-arylation of simple ketones with widely available aryl iodides, combining palladium-catalyzed ketone oxidation, aryl-halide activation, and conjugate addition through a single catalytic cycle. Simple cyclic ketones with different ring-sizes, as well as acyclic ketones, can be directly arylated at the beta-position with complete site-selectivity and excellent functional group tolerance.
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