期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 135, 期 49, 页码 18315-18318出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja410528y
关键词
-
资金
- Alexander von Humboldt Foundation
Through the use of an N-heterocyclic carbene (NHC) and the super-silyl group (tBu(3)Si), the novel silylene hydride 2 could be synthesized and isolated in 41% yield. The reaction of 2 with bis(1,5-cyclooctadiene)nickel(0) afforded complex 3, which represents the first example of a dihydrodisilene transition metal complex. Compounds 2 and 3 were fully characterized, including single-crystal X-ray diffraction analysis. The reaction mechanism for the formation of 3 from 2 was investigated by density functional theory calculations, which showed that migration of the NHC from silicon to nickel takes place in this reaction.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据