4.8 Article

Direct Construction of Quaternary Carbons from Tertiary Alcohols via Photoredox-Catalyzed Fragmentation of tert-Alkyl N-Phthalimidoyl Oxalates

期刊

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 135, 期 41, 页码 15342-15345

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AMER CHEMICAL SOC
DOI: 10.1021/ja408971t

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资金

  1. National Science Foundation [CHE1265964]
  2. National Institute of General Medical Sciences [R01GM098601]
  3. NSF
  4. NIH
  5. Direct For Mathematical & Physical Scien
  6. Division Of Chemistry [1265964] Funding Source: National Science Foundation

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A convenient method for the direct construction of quaternary carbons from tertiary alcohols by visible-light photoredox coupling of tert-alkyl N-phthalimidoyl oxalate intermediates with electron-deficient alkenes is reported.

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