期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 135, 期 4, 页码 1181-1184出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja309194z
关键词
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资金
- NSF of China [20890123, 21073043, 21210004]
- State Key Basic Research Program of the PRC [2009AA033701, 2009CB930400]
- Science and Technology Commission of Shanghai Municipality [08DZ2270500, 10JC1401800]
- Shanghai Leading Academic Discipline Project [B108]
- Australian Research Council Discovery Project [DP0986192]
- Australian Endeavour Executive Award
- Australian Research Council [DP0986192] Funding Source: Australian Research Council
Herein, we develop a reproducible in situ crystallization route to synthesize uniform functional ZSM-5 microspheres composed of aggregated ZSM-5 nanorods and well-dispersed uniform Fe3O4 nanoparticles (NPs). The growth of such unique microspheres undergoes a NP-assisted recrystallization process from surface to core. The obtained magnetic ZSM-5 microspheres possess a uniform size (6-9 mu m), ultrafine uniform Fe3O4 NPs (similar to 10 nm), good structural stability, high surface area (340 m(2)/g), and large magnetization (similar to 8.6 emu/g) and exhibit a potential application in Fischer-Tropsch synthesis.
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