期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 135, 期 45, 页码 16938-16947出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja4066267
关键词
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资金
- French Agence Nationale de Recherche (NHCX) [ANR-11-BS07-008]
- UHA
- ENSCMu
- CPE Lyon
- Universite de Lyon
- Universite Paris Diderot
- Institut Universitaire de France (IUF)
- US National Science Foundation
- CNRS
- Actelion
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1265652] Funding Source: National Science Foundation
The B-S bond in N-heterocyclic carbene (NHC)-boryl sulfides can be cleaved homolytically to NHC-boryl or NHC-thioboryl and thiyl radicals using light, either directly around 300 nm or with a sensitizer at a longer wavelength (>340 nm). In contrast, the electrochemical reductive cleavage of the B-S bond is difficult. This easy photolytic cleavage makes the NHC-boryl sulfides good type I photopolymerization initiators for the polymerization of acrylates under air.
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