期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 135, 期 13, 页码 4934-4937出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja4007645
关键词
-
资金
- MEXT
- JSPS, Japan
- Uehara Memorial Foundation
- Grants-in-Aid for Scientific Research [24106728, 25620084] Funding Source: KAKEN
A Cu-catalyzed regioselective and stereospecific aminoboration of styrenes with bis(pinacolato)diboron and O-benzoyl-N,N-dialkylhydroxylamines that delivers the corresponding beta-aminoalkylboranes in good yields has been developed. The Cu catalysis enables introduction of both amine and boron moieties to C-C double bonds simultaneously in a syn fashion. Moreover, the use of a chiral biphosphine ligand, (S,S)-Me-Duphos, provides a catalytic enantioselective route to optically active beta-aminoalkylboranes.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据