4.8 Article

Bottleable (Amino)(Carboxy) Radicals Derived from Cyclic (Alkyl)(Amino) Carbenes

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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 135, 期 50, 页码 18766-18769

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AMER CHEMICAL SOC
DOI: 10.1021/ja4104765

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  1. NSF [CHE-1316956, OCI-1053575]
  2. Division Of Chemistry
  3. Direct For Mathematical & Physical Scien [1359809] Funding Source: National Science Foundation

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Monomeric (amino)(carboxy) radicals were synthesized in two steps: the addition of a stable cyclic (alkyl) (amino) carbene to an acyl chloride, followed by a one-electron reduction. Their stability toward dimerization also allows for the synthesis of related bi- and triradicals.

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